Oxidation of the titled inner salt 1 with a typical one-electron oxidizing reagent, NOPF 6 , produced the radical cation 5a, whose dimerization, followed by loss of a sulfur atom, led to the formation of the bis-carbenium salt 4a in 95% yield. Moreover, reduction of 1 with a typical one-electron red
โฆ LIBER โฆ
ChemInform Abstract: Oxidation and Reduction of 2,2-Bis(diethylamino)-2-ethylium-1-dithioate (I).
โ Scribed by Takashi Otani; Yoshiaki Sugihara; Akihiko Ishii; Juzo Nakayama
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 27 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Oxidation and reduction of 2,2-bis(dieth
โ
Takashi Otani; Yoshiaki Sugihara; Akihiko Ishii; Juzo Nakayama
๐
Article
๐
1998
๐
John Wiley and Sons
๐
English
โ 175 KB
๐ 2 views
ChemInform Abstract: An Improved Synthes
โ
K. AKIMOTO; J. NAKAYAMA
๐
Article
๐
2010
๐
John Wiley and Sons
โ 30 KB
๐ 2 views
ChemInform Abstract: Addition of Grignar
โ
J. NAKAYAMA; T. OTANI; Y. SUGIHARA; A. ISHII
๐
Article
๐
2010
๐
John Wiley and Sons
โ 31 KB
๐ 1 views
Addition of Grignard and Organolithium Reagents to the Negatively Charged Sulfur Atom of 2,2-Bis(diethylamino)ethan-2-ylium-1dithioate. -A range of organometal nucleophiles add to the negatively charged sulfur atom of the title betaine (I) despite the presence of the positively charged carbenium io
ChemInform Abstract: Reductive Acylamina
โ
M. A. Solekhova; Yu. V. Kurbatov
๐
Article
๐
2000
๐
John Wiley and Sons
โ 27 KB
Reduction and Oxidation of 1-Methylcyclo
โ
Liliana E. Luna; Raquel M. Cravero
๐
Article
๐
2005
๐
John Wiley and Sons
โ 24 KB
ChemInform Abstract: Oxazaborolidine-Med
โ
M. SHIMIZU; K. TSUKAMOTO; T. MATSUTANI; T. FUJISAWA
๐
Article
๐
2010
๐
John Wiley and Sons
โ 37 KB