ChemInform Abstract: Oxazaborolidine-Catalyzed Reduction of Alk-2-ene-1,4-diones. A Convenient Access to Chiral 1,4-Diols.
β Scribed by Jordi Bach; Ramon Berenguer; Jordi Garcia; Marta Lopez; Judith Manzanal; Jaume Vilarrasa
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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Asymmetric Induction via an Intramolecular Haloetherification Reaction of Chiral Ene Acetals: A Novel Approach to Optically Active 1,4-and 1, 5-Diols. -A new asymmetric synthesis of chiral 1,4-(XVI) and 1,5-diols (XVIII) is developed based on remote asymmetric induction of 2 stereogenic centers int