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ChemInform Abstract: Oxazaborolidine-Catalyzed Enantioselective Reduction of 2-Acyl- thiophenes and 2-Acyl-furans.

โœ Scribed by K. R. K. PRASAD; N. N. JOSHI


Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Oxazaborolidine-Cat
โœ M. OSTENDORF; R. ROMAGNOLI; I. CABEZA PEREIRO; E. C. ROOS; M. J. MOOLENAAR; W. N ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 32 KB

Oxazaborolidine-Catalyzed Enantioselective Reduction of Cyclic meso-Imides. -It is found that several meso-imides can be reduced with high enantioselectivity by means of the oxazaborolidine shown in the scheme and subsequent ethanolysis or acetylation. By conversion to a benzenesulfonyllactam, it is