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ChemInform Abstract: Origin of the Amide Rotational Barrier

✍ Scribed by Kenneth B. Wiberg

Publisher
John Wiley and Sons
Year
2010
Weight
24 KB
Volume
31
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.

πŸ“œ SIMILAR VOLUMES

Rotational barriers of amides and polyis
Rotational barriers of amides and polyisocyanates: A spin-coupled study
✍ Guido Raos; Pietro Bielli; Elena Tornaghi πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 307 KB πŸ‘ 1 views

The spin-coupled method has been applied to the study of the rotational barriers of dimethylacetamide and of 1-acetyl-1,3,3-trimethylurea-a model compound for polyisocyanates. A significant amount of nitrogen lone-pair stabilization, achieved by delocalization toward the neighboring carbonyls, is sh