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ChemInform Abstract: Organophosphorus Compounds. Part 111. Phospha Ene Reactions of a P- Chlorophosphaalkene as a Versatile and Powerful Enophile Building Block.

✍ Scribed by T. W. MACKEWITZ; M. REGITZ


Book ID
112037403
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
27
Category
Article
ISSN
0931-7597

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Organophosphorus Compounds, 111 Phospha
✍ Mackewitz, Thomas W. ;Regitz, Manfred πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 743 KB

## Abstract [Bis(trimethylsilyl)methylene]chlorophosphane (1) has proved to act as an extremely reactive enophile in phospha ene reactions with all‐carbon enes of differing constitutions and so provides a general approach to Ξ²,γ‐unsaturated chlorophosphanes. Thus, for example, 1 reacts even at room