Organophosphorus Compounds, 111 Phospha
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Mackewitz, Thomas W. ;Regitz, Manfred
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Article
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2006
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John Wiley and Sons
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English
β 743 KB
## Abstract [Bis(trimethylsilyl)methylene]chlorophosphane (1) has proved to act as an extremely reactive enophile in phospha ene reactions with allβcarbon enes of differing constitutions and so provides a general approach to Ξ²,Ξ³βunsaturated chlorophosphanes. Thus, for example, 1 reacts even at room