## Abstract Six‐membered heterocycles, 1,4‐dithiane and 1,4‐thioxane, were treated with [Fe~2~(CO)~6~(μ‐pdt)] (pdt = propanedithiolate) in order to synthesise [2Fe3S] complexes with well positioned heteroatoms as potential base. Monosubstituted compounds of general formula [Fe~2~(CO)~5~L(μ‐pdt)] (L
ChemInform Abstract: Organometallic Diiron Complex Chemistry Related to the [2Fe]H Subsite of [FeFe]H2ase
✍ Scribed by Jean-Francois Capon; Frederic Gloaguen; Francois Y. Petillon; Philippe Schollhammer; Jean Talarmin
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 15 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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## Abstract Electrochemical investigations on a structural analogue of the [2Fe]~H~ subsite of [FeFe]H~2~ases, namely, [Fe~2~(CO)~6~{μ‐SCH~2~N(CH~2~CH~2~‐ OCH~3~)CH~2~S}] (1), were conducted in MeCN/NBu~4~PF~6~ in the presence of HBF~4~/Et~2~O or HOTs. Two different catalytic proton reduction proce