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ChemInform Abstract: Organometallic Diiron Complex Chemistry Related to the [2Fe]H Subsite of [FeFe]H2ase

✍ Scribed by Jean-Francois Capon; Frederic Gloaguen; Francois Y. Petillon; Philippe Schollhammer; Jean Talarmin


Publisher
John Wiley and Sons
Year
2008
Weight
15 KB
Volume
39
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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## Abstract Six‐membered heterocycles, 1,4‐dithiane and 1,4‐thioxane, were treated with [Fe~2~(CO)~6~(μ‐pdt)] (pdt = propanedithiolate) in order to synthesise [2Fe3S] complexes with well positioned heteroatoms as potential base. Monosubstituted compounds of general formula [Fe~2~(CO)~5~L(μ‐pdt)] (L

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## Abstract Electrochemical investigations on a structural analogue of the [2Fe]~H~ subsite of [FeFe]H~2~ases, namely, [Fe~2~(CO)~6~{μ‐SCH~2~N(CH~2~CH~2~‐ OCH~3~)CH~2~S}] (1), were conducted in MeCN/NBu~4~PF~6~ in the presence of HBF~4~/Et~2~O or HOTs. Two different catalytic proton reduction proce