ChemInform Abstract: Organomanganese Reagents. Part 35. Palladium-Catalyzed Selective Synthesis of Unsymmetrical Biaryls from Aryl Halides or Triflates and Organomanganese Reagents.

✍ Scribed by E. RIGUET; M. ALAMI; G. CAHIEZ

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 30 KB
• Volume: 28
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199738135

✦ Synopsis

Organomanganese Reagents. Part 35. Palladium-Catalyzed Selective Synthesis of Unsymmetrical Biaryls from Aryl Halides or Triflates and Organomanganese Reagents.

-Under the optimized conditions shown, the cross-coupling reaction of organomanganese halides (I) with functionalized aryl halides and triflates yields unsymmetrical biaryls. The method provides a new alternative approach to this type of compounds. -(RIGUET,