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ChemInform Abstract: Organofluorine Compounds and Fluorinating Agents. Part 22. A New Method for the Selective Introduction of Difluoromethyl and Trifluoromethyl Groups into Sugar Moieties.

✍ Scribed by R. MIETHCHEN; M. HEIN; H. REINKE

Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199831223

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We have studied the fluoroalkylation of the glucal 1 and the galactal 4 with dibromodifluoromethane via the 2-C-bromodifluoromethyl-substituted glycosyl bromides 2 and 5, respectively, followed by glycosylation to the methyl ß-D-gly-