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ChemInform Abstract: Organocatalytically Enantioselective Approach to Polysubstituted Tetrahydropyridines and Piperidines.

โœ Scribed by Fang Yu; Xiaojing Zhang; Yongwen Jiang

Publisher
John Wiley and Sons
Year
2012
Weight
51 KB
Volume
43
Category
Article
ISSN
0931-7597

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Highly Enantioselective Organocatalytic Cascade Reaction for the Synthesis of Piperidines and Oxazolidines. -Organocatalyzed Michael addition of amidomalonates, e.g. (I) and (VI), towards enals (II) followed by intramolecular hemiaminal formation provides enantioenriched piperidine derivatives (III)