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ChemInform Abstract: Organocatalytic Conjugate Addition of 2-Arylacetates and 2-Arylacetonitriles Having an Electron-Withdrawing Group to α,β-Unsaturated Ketones.

✍ Scribed by Jungho Do; Sung-Gon Kim

Publisher
John Wiley and Sons
Year
2011
Weight
33 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

The process forms the corresponding products with low diastereoselectivity.

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## Abstract The L‐valine based thiourea VTU catalyzes the reaction of nitromethane with chalcones with up to 90% enantioselectivities, whereas ketones such as (Ih)‐(Ij) give only low enantioselectivities.