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ChemInform Abstract: Organo-Substituted 1,2-Dihydro-1,2,5-disilaborepines.

โœ Scribed by B. WRACKMEYER; H. E. MAISEL; W. MILIUS

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
28
Category
Article
ISSN
0931-7597

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Organo-Substituted 1,2-Dihydro-1,2,5-Dis
Organo-Substituted 1,2-Dihydro-1,2,5-Disilaborepines
โœ Wrackmeyer, Bernd ;Maisel, Heidi E. ;Milius, Wolfgang ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 401 KB ๐Ÿ‘ 1 views

Di-1-propynyl-tetramethyldisilane (1) reacts with triorganoboranes R,B [R = Et (2a), CH2Ph (2b), Ph (2c), 2-thienyl (2d)], 9-ethyl-9-borabicyclo[3.3. llnonane (3), and diethyl(N-pyrroly1)borane (4) by twofold 1,l-organoboration to give selectively the respective organo-substituted 1,2-dihydro-1,2,5-