Zirconium Alkoxide Catalyzed Oppenauer Oxidation Using Chloral as the Hydride Acceptor. -Treatment of a variety of primary or secondary alcohols (17 examples) with anhydrous chloral in the presence of catalytic Zr(O-tBu)4 results in an effective synthesis of the corresponding aldehydes or ketones, t
ChemInform Abstract: Oppenauer Oxidation of Secondary Alcohols with 1,1,1-Trifluoroacetone as Hydride Acceptor.
β Scribed by Rossella Mello; Jaime Martinez-Ferrer; Gregorio Asensio; Maria Elena Gonzalez-Nunez
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 26 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
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Stereoselective Dehalogenation of (Z)-1-Halo-1-alkenyldialkylborane with Tributyltin Hydride: The Behavior of Tributyltin Hydride as a Hydride Donor. -While the dehalogenation of the alkylboranes (Ia) and (Ib) leads stereoselectively to the corresponding (E)-alkenes, the change of bulkiness of the
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