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ChemInform Abstract: One-Pot Synthesis of Cyclobutanols by Ring Expansion of Oxaspiropentanes Induced by Grignard Reagents.

✍ Scribed by A. M. BERNARD; C. FLORIS; A. FRONGIA; P. P. PIRAS

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199839058

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Stereocontrolled Synthesis of Spiro[n.2]alkenes by Ring Contraction of Fused-Cyclobutanols. -The present newly developed unusual ring contraction rearrangement leads to spirocyclopropanes from fused cyclobutanols. In contrast to bicyclo[4.2.0]octanol derivatives (I) which are exclusively converted i