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ChemInform Abstract: One-Pot Construction of Multi-Substituted Spiro-Cycloalkanediones by an Organocatalytic Asymmetric Epoxidation/Semipinacol Rearrangement.

✍ Scribed by Bao-Sheng Li; En Zhang; Qing-Wei Zhang; Fu-Min Zhang; Yong-Qiang Tu; Xiao-Ping Cao


Publisher
John Wiley and Sons
Year
2011
Weight
46 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

High stereoselectivity in an aqueous medium, the introduction of tri‐oxygenated functional groups, and the efficient construction of at least two chiral centers are features of this transformation.