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ChemInform Abstract: On the Scope of Trimethylaluminum-Promoted 1,2-Additions of ArZnX Reagents to Aldehydes.

✍ Scribed by Daniel Glynn; Jonathan Shannon; Simon Woodward

Publisher
John Wiley and Sons
Year
2010
Weight
57 KB
Volume
41
Category
Article
ISSN
0931-7597

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On the Scope of Trimethylaluminium-Promo
On the Scope of Trimethylaluminium-Promoted 1,2-Additions of ArZnX Reagents to Aldehydes
✍ Daniel Glynn; Jonathan Shannon; Simon Woodward πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 330 KB

## Abstract A practical asymmetric 1,2‐addition of functionalised arylzinc halides to aromatic and aliphatic aldehydes is described by the use of aminoalcohol catalysis in the presence of AlMe~3~. The process is simple to carry out, uses only commercially available reagents/ligands and provides mod