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ChemInform Abstract: Oligomeric Tetrahedral Anions in Borophosphates: Synthesis and Crystal Structures of NaFe[BP2O7(OH)3] and K2Fe2 [B2P4O16(OH)2].

✍ Scribed by I. BOY; G. CODIER; B. EISENMANN; R. KNIEP


Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
29
Category
Article
ISSN
0931-7597

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compound (III) crystallizes in the monoclinic space group P2 1 /c with Z = 2 (single crystal XRD). The structure contains oligomeric tetrahedral anions based on six-membered rings of four BO 4 and two PO 4 tetrahedra with additional branchings by hydrogenphosphate groups (two cyclic, four open branc