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ChemInform Abstract: Olefin Cyclopropanation Catalyzed by Bis(imido) Chromium(VI) Complexes.

✍ Scribed by Dominique Jan; Francois Simal; Albert Demonceau; Alfred F. Noels; Konstantin A. Rufanov; Nikolai A. Ustynyuk; Dmitry N. Gourevitch

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Olefin Cyclopropanation Catalyzed by Bis(imido) Chromium(VI) Complexes.

-The cyclopropanation of activated and unactivated olefins with ethyl diazoacetate in the presence of catalytic bis(imido) chromium(VI) complexes is investigated.

Cycloolefins and non-activated terminal linear olefins are found to be almost unreactive.

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