ChemInform Abstract: Obtention of Two Anomers of Imidazolone During the Type I Photosensitized Oxidation of 2′-Deoxyguanosine.

✍ Scribed by Corine Vialas; Genevieve Pratviel; Albert Meyer; Bernard Rayner; Bernard Meunier

• Book ID: 101883247
• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 31 KB
• Volume: 30
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199938204

✦ Synopsis

Obtention of Two Anomers of Imidazolone During the Type I Photosensitized Oxidation of 2'-Deoxyguanosine.

-The main product in the title reaction, which is investigated in detail, is the β-anomer (II). It is noteworthy that the chemical oxidation with an artificial nuclease system leads in nearly quantitative yield to the compounds (II) and (III) from (I) or its corresponding α-anomer, respectively. -(VIALAS, CORINE;