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ChemInform Abstract: Nucleophilic Ring Opening of Cyclic 1,2-Sulfites with Nitrogen Nucleophiles. A Route to Enantiopure Benzylic Amino Alcohols.

โœ Scribed by K. NYMANN; S. MYLVAGANAM; J. S. SVENDSEN


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
29
Category
Article
ISSN
0931-7597

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โœ R. N. WARRENER; A. S. AMARASEKARA ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 31 KB ๐Ÿ‘ 1 views

Thermal Isomerization to 1,4-Thiazine-S-oxides and Nucleophilic Ring-Opening with Alcohols and Amines. -Thiazetidines (III), readily produced by cycloaddition of quadricyclane with aryl sulfonylamines undergo smooth thermal rearrangement to thiazines like (IV) with S-oxide configuration that differ