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ChemInform Abstract: Nucleophilic Phosphine-Catalyzed Iodocyclization of Isoprenoids Bearing an Oxygen Terminal Group.

✍ Scribed by Akira Sakakura; Gakujun Shomi; Atsushi Ukai; Kazuaki Ishihara


Book ID
102058907
Publisher
John Wiley and Sons
Year
2011
Weight
45 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

Tbs‐ether of homogeraniol and Tbs‐ester of homogeranic acid are successfully converted to the corresponding iodopolycyclic products in the presence of a catalytic amount of triphenylphosphine with complete diastereoselectivity.


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