ChemInform Abstract: Nucleophilic Displacement of Homoallylic Tosylates: Influence of Steric Hindrance and Conformational Rigidity.

ChemInform Abstract: Influence of the St

ChemInform Abstract: Influence of the Steric Hindrance of the Aryl Group of Pentavalent Triarylbismuth Derivatives in Ligand Coupling Reactions.

✍ Alexey Fedorov; Sebastien Combes; Jean-Pierre Finet 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB 👁 1 views

Influence of the Steric Hindrance of the Aryl Group of Pentavalent Triarylbismuth Derivatives in Ligand Coupling Reactions. -Basepromoted reaction of tris(ortho-tolyl)bismuth dichloride with nucleophiles leads to C-arylated products in good yields. Starting from bulkier trimestitylbismuth dichloride