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ChemInform Abstract: Novel Solid-State Synthesis of Dimeric 4-Aryl-1,4-dihydropyridines.

✍ Scribed by A. HILGEROTH; F. W. HEINEMANN

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199837176

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✦ Synopsis

Novel Solid-State Synthesis of Dimeric 4-Aryl-1,4-dihydropyridines. -On irradiation in the solid state, 4-aryldihydropyridines (I) and (IV) undergo [2 + 2] cycloaddition to centrosymmetric head-to-tail dimers (II) and (V), respectively. Further irradiation of the dimers (II) provides the cage dimers (III) by reaction of the remaining neighboring double bonds. Contrary, photoadduct (V) remains stable on further irradiation. -(HILGEROTH, A.;

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