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ChemInform Abstract: Novel [Ruthenium(substituted-tetramethylcyclopentadiene) (2-quinolinecarboxylato)(allyl)] Hexafluorophosphate Complexes as Efficient Catalysts for Highly Regioselective Nucleophilic Substitution of Aliphatic Allylic Substrates.

✍ Scribed by Hui-Jun Zhang; Bernard Demerseman; Loic Toupet; Zhenfeng Xi; Christian Bruneau

Publisher
John Wiley and Sons
Year
2008
Weight
49 KB
Volume
39
Category
Article
ISSN
0931-7597

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Abstract

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Novel [Ruthenium(substituted-tetramethyl
Novel [Ruthenium(substituted-tetramethylcyclopentadiene) (2-quinolinecarboxylato)(allyl)] Hexafluorophosphate Complexes as Efficient Catalysts for Highly Regioselective Nucleophilic Substitution of Aliphatic Allylic Substrates
✍ Hui-Jun Zhang; Bernard Demerseman; Loïc Toupet; Zhenfeng Xi; Christian Bruneau 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 245 KB 👁 1 views

## Abstract Stable [ruthenium(R‐substituted‐tetramethylcyclopentadiene)(2‐quinolinecarboxylato)(1‐R′‐substituted‐allyl) hexafluorophosphate (R=Me, R′=H, Me, __n‐__Pr, Ph; R=__t‐__Bu, R′=Me) and [ruthenium(pentamethylcyclopentadiene)(2‐quinolinecarboxylato)(1‐__n__‐propylallyl)] tetrafluoroborate (*