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ChemInform Abstract: Novel Rearrangement Reactions in the Fluorination of Methyl 3-C-Methyl- 3-nitro-α-L-hexopyranosides by the DAST Reagent.

✍ Scribed by P. BORRACHERO-MOYA; F. CABRERA-ESCRIBANO; M. GOMEZ-GUILLEN; F. MADRID-DIAZ


Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
28
Category
Article
ISSN
0931-7597

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Studies of the Synthesis of Rubranitrose and Crystal Structure of Methyl 2,3,6-Trideoxy-3-C-methyl-3-nitro-α-D-ribo-hexopyranoside. -The title hexopyranoside (II) is investigated as a precursor to D-rubranitrose, a nitro sugar found in the antibiotic rubradirin. -(YE, H.; NOECKER,