ChemInform Abstract: Novel Reactions of 2-Carbomethoxymethyl-2-thiophenyl-8-oxabicyclo(3.2. 1)octan-3-one.
β Scribed by M. M. M. RUBINGER; J. MANN; M. G. B. DREW
- Book ID
- 112026986
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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Enantioselective Deprotonation of the 8-Oxabicyclo[3.2.1]octan-3-one: Synthesis of 8-Oxa-norcocaines and 8-Oxa-pseudonorcocaines. -Asymmetric deprotonation of the racemic ketone (I) using chiral lithium amides provides ready access to the non-racemic Ξ²-ketoesters (III), which can be easily transfor
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