ChemInform Abstract: Novel Products from Bromination Reactions of 5,10,15,20-Tetraisopropylporphyrins.

✍ Scribed by N. Y. NELSON; C. J. MEDFORTH; R. G. KHOURY; D. J. NURCO; K. M. SMITH

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 36 KB
• Volume: 29
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199847125

✦ Synopsis

Novel Products from Bromination Reactions of 5,10,15,20-Tetraisopropylporphyrins.

-Bromination reactions of Ni(II) and Cu(II) complexes of tetraisopropylporphyrin (I) and (V), resp., afford unusual porphodimethenes (II), (III), (IV), and (VI) depending on the bromination conditions. Crystallographic data for some of these compounds are given and possible mechanisms are discussed. -(NELSON, N. Y.; MEDFORTH,