ChemInform Abstract: Novel One-Dimensional Organic Conductor Based on Selenium-Containing Bis-Fused Tetrathiafulvalene Derivative, (TSM-TTP)(I3)5/3.
✍ Scribed by T. MORI; T. KAWAMOTO; Y. MISAKI; K. TANAKA
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 36 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
1998 organo-selenium compounds, heterocyclic C derivatives organo-selenium compounds, heterocyclic C derivatives S 0136
39 -196
Novel One-Dimensional Organic Conductor Based on Selenium-Containing Bis-Fused Tetrathiafulvalene Derivative, (TSM-TTP)(I 3 ) 5/3 . -TSM-TTP (VI), a methylseleno analogue of TTM-TTP is prepared. TSM-TTP forms a 3:5 triiodide salt, (TSM-TTP)(I 3 ) 5/3 . The 1:1 salt (TSM-TTP)I 3 is not obtained. The title salt possesses uniform one-dimensional columns of the donors and is isostructural to the corresponding complex of the sulfur analogue. The novel compound displays high electrical conductivity and undergoes a metal-insulator transition around 20 K. -(MORI, T.;