ChemInform Abstract: Novel Efficient Synthesis of β-Fluoro-β-(trifluoromethyl)styrenes.
✍ Scribed by Aleksey A. Goldberg; Vasiliy M. Muzalevskiy; Aleksey V. Shastin; Elisabeth S. Balenkova; Valentine G. Nenajdenko
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 27 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
A Novel Efficient Synthesis of Heteroaryl Substituted α,β-Unsaturated Trifluoromethyl Ketones. -The novel electrophilic reagent (IV), easily prepared by reaction of phenyl vinyl sulfide and trifluoroacetic anhydride followed by oxidation with peroxytrifluoroacetic acid, reacts with electron-rich he
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## Abstract The palladium/copper(I) iodide cocatalyzed coupling reaction of (Z)‐α‐fluoro‐β‐trifluoromethylstannanes (**1**) with vinyl iodides (**2**) has been explored giving substituted α‐fluoro‐β‐trifluoromethyl dienes (**3**) in 33–95% yields. In studies we have conducted so far, a larger numbe