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ChemInform Abstract: Novel Diamino and Diimino Thioethers — Chiral Tridentate Ligands for Asymmetric Michael Reactions?

✍ Scribed by Jens Christoffers; Alexander Mann

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
30
Category
Article
ISSN
0931-7597

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Novel Diamino and Diimino Thioethers – C
Novel Diamino and Diimino Thioethers – Chiral Tridentate Ligands for Asymmetric Michael Reactions?
✍ Jens Christoffers; Alexander Mann 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 234 KB 👁 1 views

Novel C 2 -symmetric enantiopure β,βЈ-diamino thioethers 1 achieving the enantioselective catalysis of a Michael reaction of a β-oxo ester with methyl vinyl ketone resulting in an and β,βЈ-diimino thioethers 2 have been prepared from chiral α-amino acids. Nine of these compounds have been screened