ChemInform Abstract: Novel Coordination Modes for E4S3 Cage Molecules (E: P, As) in Unprecedented Quaternary As4S3(CuCl)n (n = 1,2) Solid-State Phases.

Novel Coordination Modes for E4S3 Cage M

Novel Coordination Modes for E4S3 Cage Molecules (E = P, As) in Unprecedented Quaternary As4S3(CuCl)n (n = 1,2) Solid-State Phases

✍ Patrick Schwarz; Joachim Wachter; Manfred Zabel 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 273 KB 👁 1 views

## Abstract First examples of the coordination chemistry of the As~4~S~3~ cage were obtained from solutions of As~4~S~3~·M(CO)~5~ (M = Cr, W) in CH~2~Cl~2~ and CuCl__~n~__ in CH~3~CN (__n__ = 1) or CH~3~OH (__n__ = 2) through interdiffusion techniques. The compounds (As~4~S~3~)(CuCl)__~n~__ (1: __n