ChemInform Abstract: Novel Concepts in Directed Biaryl Synthesis. Part 76. First Synthesis of Mastigophorenes A and B, by Biomimetic Oxidative Coupling of Herbertenediol.

✍ Scribed by Gerhard Bringmann; Thomas Pabst; David S. Rycroft; Joseph D. Connolly

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 29 KB
• Volume: 30
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199917256

✦ Synopsis

Novel Concepts in Directed Biaryl Synthesis. Part 76. First Synthesis of Mastigophorenes A and B, by Biomimetic Oxidative Coupling of Herbertenediol.

-The first synthesis of the title compounds (I), which are atropisomers, by oxidative phenolic coupling of partially protected derivatives of their joint natural monomeric half, herbertenediol, is described.