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ChemInform Abstract: Novel Chiral Thiazoline-Containing N—O Ligands in the Asymmetric Addition of Diethylzinc to Aldehydes: Substituent Effect on the Enantioselectivity.

✍ Scribed by Zhiyong Gong; Qingwen Liu; Pengchong Xue; Kechang Li; Zhiguang Song; Zaiqun Liu; Yinghua Jin


Book ID
112047997
Publisher
John Wiley and Sons
Year
2012
Weight
32 KB
Volume
43
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Dramatic Temperatur
✍ Huichang Zhang; Kin Shing Chan 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 2 views

Dramatic Temperature Effect in Asymmetric Catalysis in the Enantioselective Addition of Diethylzinc to Aldehydes. -The enantioselectivity of the addition of Et 2 Zn to aryl aldehydes in the presence of catalytic amounts of a chiral pyridyl-phenol ((S)-MPBP) is found to depend heavily on temperature