ChemInform Abstract: Novel Asymmetric Desymmetrization of meso-1,2-Diols via Diastereoselective β-Elimination of Chiral α-Arylsulfinyl Acetals.
✍ Scribed by N. MAEZAKI; M. SOEJIMA; M. TAKEDA; A. SAKAMOTO; Y. MATSUMORI; T. TANAKA; C. IWATA
- Book ID
- 112036551
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 33 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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Desymmetrization of meso-1,2-Diols via Chiral Oxazaborolidine-Mediated Ring-Cleavage of Acetal Derivatives with Silyl Ketene S,O-Acetal. -The desymmetrization of a variety of meso-1,2-diols is readily achieved by chiral oxazaborolidine-mediated enantioselective ring cleavage of acetals of type syn-