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ChemInform Abstract: NMR Study of Stereoelectronic Anomeric and Homoanomeric Effects on the Axial and Equatorial CH Bonds in 1,3-Diazacyclohexanes and 1,5-Diazabicyclo[3.2.1]octanes

✍ Scribed by J. E. ANDERSON; J. CAI; A. G. DAVIES


Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
29
Category
Article
ISSN
0931-7597

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The conÐguration and conformation of cis/trans-3,4-dihydro-2-alkoxy-4-(alkylor aryl-substituted)-2H,5Hpyrano [ 3,2-c ] [1]benzopyran-5-one derivatives were studied by combined NMR and computational analyses. The cis/trans conÐgurational assignments of all diastereoisomers were achieved via 2D NOESY