ChemInform Abstract: Nickel-Catalyzed Preparations of Functionalized Organozincs.

✍ Scribed by S. VETTEL; A. VAUPEL; P. KNOCHEL

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 32 KB
• Volume: 28
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199708083

✦ Synopsis

Nickel-Catalyzed Preparations of Functionalized Organozincs.

-A new synthesis of functionalized organo-Zn compounds and their reactions with various electrophiles after transmetalation with CuCN are presented. The method is also used in asymmetric synthesis with (R, R)-1,2-bis(trifluoromethanesulfonamido)cyclohexane as catalyst.

-(VETTEL,