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ChemInform Abstract: Nickel-Catalyzed Coupling Reaction of Sterically Congested cis Bromides and Lithium Alkenylborates.

✍ Scribed by Y. KOBAYASHI; Y. NAKAYAMA; R. MIZOJIRI


Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
29
Category
Article
ISSN
0931-7597

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## Abstract The coupling reaction of the α‐bromoalkenylphosphonates with organoboranes was investigated. The palladium‐catalyzed arylation took place successfully with arylboronic acids, while alkenylation proceeded with lithium alkenylborates and a nickel catalyst. In addition, an intramolecular D