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ChemInform Abstract: Nickel-Catalyzed Benzylic Oxidation with NaOCl.

✍ Scribed by Shigekazu Yamazaki

Publisher: John Wiley and Sons
Year: 2010
Weight: 29 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199934074

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✦ Synopsis

Nickel-Catalyzed Benzylic Oxidation with NaOCl.

-NiCl 2 (bipy) 2 is found to be an efficient catalyst for the oxidation of various alkylbenzenes with hypochlorite. Best results are obtained in the oxidation of toluenes bearing electron-withdrawing substituents in the p-position. -(YAMAZAKI,

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