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ChemInform Abstract: Nickel-Catalyzed 1,4-Addition of Aryl Groups to Enones Using Aryldialkylaluminum Compounds.

✍ Scribed by J. WESTERMANN; U. IMBERY; NGUYEN ANH THU NGUYEN ANH THU; K. NICKISCH

Publisher: John Wiley and Sons
Year: 2010
Weight: 33 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199823064

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The transmetallation of arylmagnesium halides or aryllithium Ni(acac) 2 as a catalyst. 3-Aryl ketones are obtained in good yields in these catalytic reactions. Starting from the 3-oxo-with Me 2 AlCl results in the formation of aryldimethylaluminum compounds. These arylaluminum compounds are useful ∆

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ChemInform Abstract: Rhodium-Catalyzed Asymmetric 1,4-Addition of Aryl- and Alkenylboronic Acids to Enones.

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ChemInform Abstract: Enantioselective Copper-Catalyzed 1,4-Addition of Organozinc Reagents to Enones Using Chiral Oxazoline-Phosphite Ligands.

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Enantioselective Copper-Catalyzed 1,4-Addition of Organozinc Reagents to Enones Using Chiral Oxazoline-Phosphite Ligands. -The enantioselective 1,4-addition of organozinc reagents to α,β-unsaturated ketones in the presence of chiral P,N-ligands (I) with a binaphthyl phosphite group and an oxazoline

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