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ChemInform Abstract: (Ni3-xMgx) [B3P3O12(OH)6] ×6H2O (x = 1.5): A Novel Borophosphate-Hydrate Containing Isolated Six-Membered Rings of Tetrahedra.

✍ Scribed by Insan Boy; Gerd Schaefer; Ruediger Kniep


Publisher
John Wiley and Sons
Year
2001
Weight
39 KB
Volume
32
Category
Article
ISSN
0931-7597

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(Ni3–xMgx)[B3P3O12(OH)6] · 6 H2O (x ≈ 1.
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A novel borophosphate-hydrate, (Ni 3±x Mg x )-[B 3 P 3 O 12 (OH) 6 ] ´6 H 2 O (x » 1.5), has been prepared by hydrothermal synthesis (T = 170 °C) from a mixture of NiCl 2 ´6 H 2 O, Mg(OH) 2 , B 2 O 3 and H 3 PO 4 . The crystal structure was determined at 293 K from single-crystal X-ray diffraction d

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