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ChemInform Abstract: New δ-Aminoalcohol for the Enantioselective Addition of Dialkylzincs to Aldehydes.

✍ Scribed by M. GENOV; V. DIMITROV; V. IVANOVA


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
29
Category
Article
ISSN
0931-7597

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Catalyzed asymmetric dialkylzinc additio
✍ V.M. Demyanovich; I.N. Shishkina; N.S. Zefirov 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 93 KB

## Abstract A series of δ‐aminoalcohols prepared from (S)‐ and (R)‐N,N‐dimethyl‐1‐phenethylamines was found to catalyze the enantioselective addition of diethylzinc to benzaldehyde to yield optically active 1‐phenylpropanol with enantiomeric excess 60–85%. Chirality 13:507–509, 2001. © 2001 Wiley‐L