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ChemInform Abstract: New Vinylogous Tetrathiafulvalene π-Electron Donors with Lower Oxidation Potentials.

✍ Scribed by L. YU; D. ZHU

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199735135

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✦ Synopsis

New Vinylogous Tetrathiafulvalene π-Electron Donors with Lower Oxidation Potentials.

-Mild and efficient syntheses of new vinylogous tetrafulvalenes (VI) and 1,3-dithiole-2-thiones (V) via base-catalyzed ring opening of (III) are described. Cyclic voltammetry establishes that the new donors (VI) have significantly lower solution oxidation potentials than the already known organic superconductor bis(ethylenedithiol) tetrathiafulvalene and therefore behave as good precursors for organic metals. -(YU, L.; ZHU,

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