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ChemInform Abstract: New Stereoselective Synthesis of (.+-.)-trans-2-Butyl-5-heptyl-1-methylpyrrolidine, Ant Venom Alkaloid, by Aminyl Radical Cyclization.

✍ Scribed by Hisanori Senboku; Hikaru Hasegawa; Kazuhiko Orito; Masao Tokuda


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis


New Stereoselective Synthesis of (±)-trans-2-Butyl-5-heptyl-1methylpyrrolidine, Ant Venom Alkaloid, by Aminyl Radical Cyclization. -The key step in the synthesis of title alkaloid (II) is a stereoselective cyclization of an aminyl radical derived from (I). -(SENBOKU, HISANORI;