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ChemInform Abstract: New Frequency Doubling Compounds: K4Ln2(CO3)3F4 (Ln: Pr, Nd, Sm, Gd, Eu); Crystal Structure and Characterization.

✍ Scribed by N. MERCIER; M. LEBLANC; J. DURAND

Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199738025

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✦ Synopsis

The title compounds are prepared by hydrothermal reaction of K2CO3 and LnF3 at 740 • C and 220 MPa. The isostructural compounds crystallize in the rhombohedral space group R32 with Z = 3. The structure consists of KLn2(CO3)3 carbonate and K3F4 fluoride sheets. K4Eu2(CO3)3F4 exhibits a frequency doubling efficiency similar to that of N.;

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