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ChemInform Abstract: New Examples for the Unexpected Stability of the 10π-Electron Hueckel Arene [Si6]10-.

✍ Scribed by Raul Cardoso Gil; Wilder Carrillo-Cabrera; Martin Schultheiss; Karl Peters; Hans Georg von Schnering

Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
30
Category
Article
ISSN
0931-7597

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New Examples for the Unexpected Stabilit
New Examples for the Unexpected Stability of the 10π-Electron Hückel Arene [Si6]10–
✍ Raul Cardoso Gil; Wilder Carrillo-Cabrera; Martin Schultheiss; Karl Peters; Hans 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 524 KB

The compounds Ba 4 Ag 2 Si 6 , Eu 4 Ag 2 Si 6 , and Ca 4 Ag 2 Si 6 , prepared from the elements at 1273 K (the components in inner corundum crucibles are enclosed in sealed quartz ampoules), are brittle semiconductors with silvery luster. They react slowly with acids liberating hydrogen. Ba 4 Ag 2 [

ChemInform Abstract: Synthesis and Cryst
ChemInform Abstract: Synthesis and Crystal Structure of the New Metal-Rich Ternary Borides Ni12AlB8, Ni12GaB8 and Ni10.6Ga0.4B6 — Examples for the First B5 Zig-Zag Chain Fragment.
✍ Martin Ade; Dominik Kotzott; Harald Hillebrecht 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 17 KB 👁 2 views

## Abstract Single crystals of the new title compounds are prepared from the elements (Ar, 1250—1450 °C, 1—6 h) and their structures are determined by single crystal XRD.