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ChemInform Abstract: New Dihydro and Tetrahydro Derivatives of Desmycosin. Part 3. The Opening of Oxirane Ring of 12,13-Epoxydesmycosin.

✍ Scribed by A. NARANDA; N. LOPOTAR; Z. KELNERIC

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

New Dihydro and Tetrahydro Derivatives of Desmycosin. Part 3. The Opening of Oxirane Ring of 12,13-Epoxydesmycosin.

-The catalytic hydrogenation of (I) to form (II) and the reductive oxirane-ring opening of same starting compound (I) yielding (III) fail in creating new antibacterially active derivatives. Mild acid hydrolysis of (II) gives three inactive desepoxy diols.

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