ChemInform Abstract: New Chiral 3-Aryl-7-arylmethylidene-3,3a,4,5,6,7-hexahydroindazoles: Synthesis, Structure, and Twisting Power in Nematic Liquid Crystals.
β Scribed by V. V. Abakumov; N. S. Pivnenko; L. A. Kutulya; I. S. Konovalova; A. D. Roshal'; N. B. Novikova; O. V. Shishkin
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 32 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
Starting from (3R)β3βmethylcyclohexanone, compounds (III), (V) and a range of alkylβsubstituted analogues are prepared stereoselectively in low to medium yields for application as chiral additives in liquid crystalline materials.
π SIMILAR VOLUMES
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Synthesis and Dimroth Rearrangement of 6-Cyano-1,2,4-triazolo[4,3a]pyrimidin-5-and 7-ones. A Novel Alkylation with Orthoesters and a New Participation of the Cyano Group in the Rearrangement. -Formic acid and triethyl orthoformate react with 2-hydrazinopyrimidin-4-ones (I) and (VI) to furnish triazo