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ChemInform Abstract: New Barium Niobium Sulfides. Part 2. Preparation of BaNb2.85S6.23 and BaNb5.33S11.0.

✍ Scribed by M. SAEKI; Y. YAJIMA


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis


New Barium Niobium Sulfides. Part 2. Preparation of BaNb2.85S6.23 and BaNb5.33S11.0.

-Pure single phase BaNb2.85S6.23 (I) is prepared from a starting sulfide, obtained within 3 d from BaCO3 and Nb2O5 (Nb/Ba = 2.85) in CS2 at 750 β€’ C, by controlling the partial pressure of sulfur. Single phase BaNb5.33S11.0 (II) is synthesized by heating the starting sulfide (Nb/Ba = 5.33) with extra sulfur for 5 d at 1000 β€’ C. The powder XRD patterns of (I) and (II) are indexed in a hexagonal setting, and the electron diffraction data reveal a superstructure of 3a x 3a.


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