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ChemInform Abstract: New Asymmetric Transformation of Optically Active Allene-1,3-dicarboxylate and Its Application to the Formal Asymmetric Synthesis of (-)-Epibatidine.

✍ Scribed by M. NODE; K. NISHIDE; T. FUJIWARA; S. ICHIHASHI

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

New Asymmetric Transformation of Optically Active Allene-1,3dicarboxylate and Its Application to the Formal Asymmetric Synthesis of (-)-Epibatidine.

-The synthesis of optically active allene-1,3-dicarboxylate (II) involving asymmetric transformation through epimerization-crystallization and its application to the asymmetric synthesis of (VI), a synthetic intermediate of (-)-epibatidine, is described. -(NODE, M.;

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