✦ LIBER ✦
ChemInform Abstract: New Access to Methyl Formylcyclopropanecarboxylates via Diethylaminotrimethylsilane Mediated Tandem Nucleophilic Reaction of Aldehyde with Methyl 2,3-Dihalopropanoate.
✍ Scribed by Hisahiro Hagiwara; Nao Komatsubara; Takashi Hoshi; Toshio Suzuki; Masayoshi Ando
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
New Access to Methyl Formylcyclopropanecarboxylates via Diethylaminotrimethylsilane Mediated Tandem Nucleophilic Reaction of Aldehyde with Methyl 2,3-Dihalopropanoate.
-The title reaction results in formation of diastereomeric mixtures of formylcyclopropanecarboxylates. In some cases [cf. (V)/(VI)] these mixtures can be separated.