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ChemInform Abstract: Neutron Powder Diffraction Study of the Dehydration of Zeolite N.

✍ Scribed by A. Noerlund Christensen; H. Fjellvaag

Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199916014

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✦ Synopsis

1999 structure structure (solids and liquids) D 2000

16 -014

Neutron Powder Diffraction Study of the Dehydration of Zeolite N. -Zeolite N with the composition K 12 Al 10 Si 10 O 40 Cl 2 •8H 2 O is pseudotetragonal with an EDI type structure. The orthorhombic cell shows the space group I222 with Z = 1 at 293 K. The powder neutron diffraction pattern are analyzed in the range 293-623 K and they show that the dehydration process between 373 and 623 K is connected with the rearrangement of the Cl and K atoms. The driving force for this process is probably the strive for acceptable coordination of the salt-like components. -(CHRISTENSEN, A.

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